It sounds like combustion, but it's not. Combustion uses an abundance of oxygen to produce heat and light by burning. Gasification uses only a tiny amount of oxygen, which is combined with steam and cooked under intense pressure. This initiates a series of reactions that produces a gaseous mixture composed primarily of carbon monoxide and hydrogen. This syngas can be burned directly or used as a starting point to manufacture fertilizers, pure hydrogen, methane or liquid transportation fuels.
Believe it or not, gasification has been around for decades. Scottish engineer William Murdoch gets credit for developing the basic process. In the late 1790s, using coal as a feedstock, he produced syngas in sufficient quantity to light his home. Eventually, cities in Europe and America began using syngas -- or "town gas" as it was known then -- to light city streets and homes. Eventually, natural gas and electricity generated from coal-burning power plants replaced town gas as the preferred source of heat and light.
Today, with a global climate crisis looming on the horizon and power-hungry nations on the hunt for alternative energy sources, gasification is making a comeback. The Gasification Technologies Council expects world gasification capacity to grow by more than 70 percent by 2015. Much of that growth will occur in Asia, driven by rapid development in China and India. But the United States is embracing gasification, as well.
Let's take a closer look at how this process works. We're going to start with coal gasification, the most common form of the process.
The heart of a coal-fired power plant is a boiler, in which coal is burned by combustion to turn water into steam. The following equation shows what burning coal looks like chemically: C + O2 --> CO2. Coal isn't made of pure carbon, but of carbon bound to many other elements. Still, coal's carbon content is high, and it's the carbon that combines with oxygen in combustion to produce carbon dioxide, the major culprit in global warming. Other byproducts of coal combustion include sulfur oxides, nitrogen oxides, mercury and naturally occurring radioactive materials.
The heart of a power plant that incorporates gasification isn't a boiler, but a gasifier, a cylindrical pressure vessel about 40 feet (12 meters) high by 13 feet (4 meters) across. Feedstocks enter the gasifier at the top, while steam and oxygen enter from below. Any kind of carbon-containing material can be a feedstock, but coal gasification, of course, requires coal. A typical gasification plant could use 16,000 tons (14,515 metric tons) of lignite, a brownish type of coal, daily.
A gasifier operates at higher temperatures and pressures than a coal boiler -- about 2,600 degrees Fahrenheit (1,427 degrees Celsius) and 1,000 pounds per square inch (6,895 kilopascals), respectively. This causes the coal to undergo different chemical reactions. First, partial oxidation of the coal's carbon releases heat that helps feed the gasification reactions. The first of these is pyrolysis, which occurs as coal's volatile matter degrades into several gases, leaving behind char, a charcoal-like substance. Then, reduction reactions transform the remaining carbon in the char to a gaseous mixture known as syngas.
Carbon monoxide and hydrogen are the two primary components of syngas. During a process known as gas cleanup, the raw syngas runs through a cooling chamber that can be used to separate the various components. Cleaning can remove harmful impurities, including sulfur, mercury and unconverted carbon. Even carbon dioxide can be pulled out of the gas and either stored underground or used in ammonia or methanol production.
